What is the difference between formic acid and sodium formate?

1.Chemical structure:

Formic acid (HCOOH): It is a simple carboxylic acid with the chemical formula HCOOH. It consists of a carboxyl group (COOH), where a hydrogen is attached to a carbon and another oxygen forms a double bond with the carbon.

Sodium formate (HCCONa): It is the sodium salt of formic acid. The carboxylic hydrogens in formic acid are replaced by sodium ions, forming sodium formate.

2. Physical properties:

Formic acid:
At room temperature, formic acid is a colorless liquid with a pungent odor.
Its boiling point is 100.8 degrees Celsius.
Formic acid is miscible with water and many organic solvents.
Sodium formate:
Sodium formate usually comes in the form of a white hygroscopic powder.
It is soluble in water but has limited solubility in some organic solvents.
Due to its ionic nature, this compound has a higher melting point compared to formic acid.

3. Acidic or alkaline:

Formic acid:
Formic acid is a weak acid that can donate protons (H+) in chemical reactions.
Sodium formate:
Sodium formate is a salt derived from formic acid; it is not acidic. In aqueous solution, it decomposes into sodium ions (Na+) and formate ions (HCOO-).

4. Purpose:

Formic acid:

It is commonly used in the production of leather, textiles and dyes.
Formic acid is an important component in the processing of animal hides and skins in the leather industry.
It is used as a reducing agent and preservative in some industries.
In agriculture, it is used as a feed additive to inhibit the growth of certain bacteria and fungi.
Sodium formate:

Sodium formate is used as a de-icing agent for roads and runways.
Used as reducing agent in printing and dyeing industry.
This compound is used in drilling mud formulations in the oil and gas industry.
Sodium formate is used as a buffering agent in some industrial processes.

5. Production:

Formic acid:

Formic acid is produced by the catalytic hydrogenation of carbon dioxide or the reaction of methanol with carbon monoxide.
Industrial processes involve the use of catalysts and high temperatures and pressures.
Sodium formate:

Sodium formate is usually produced by neutralizing formic acid with sodium hydroxide.
The resulting sodium formate can be isolated by crystallization or obtained in solution form.

6. Safety precautions:

Formic acid:

Formic acid is corrosive and can cause burns on contact with skin.
Inhalation of its vapors may cause irritation to the respiratory system.
Sodium formate:

Although sodium formate is generally considered less hazardous than formic acid, proper handling and storage precautions still need to be taken.
Safety guidelines must be followed when using sodium formate to avoid potential health risks.

7. Environmental impact:

Formic acid:

Formic acid can biodegrade under certain conditions.
Its impact on the environment is affected by factors such as concentration and exposure time.
Sodium formate:

Sodium formate is generally considered environmentally friendly and has a lower impact than some other de-icers.

8. Cost and Availability:

Formic acid:

The cost of formic acid can vary depending on production method and purity.
It can be purchased from various suppliers.
Sodium formate:

Sodium formate is priced competitively and its supply is affected by demand from different industries.
It is prepared by neutralizing formic acid and sodium hydroxide.

Formic acid and sodium formate are different compounds with different properties and applications. Formic acid is a weak acid used in a wide range of applications, from industrial processes to agriculture, while sodium formate, the sodium salt of formic acid, is used in areas such as de-icing, textiles and the oil and gas industry. Understanding their properties is critical for safe handling and effective utilization in various fields.


Post time: Dec-06-2023